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"Purgatory Girl" is the 13th episode of the season "Jigoku Shoujo".
Ai Enma isn't just a recent phenomenon, but one occurring for hundreds of years. This episode showed how the Hell Correspondence was accessed in the past through the classified ads. A man named Fukumoto sent a man named Okochi to hell using the method, and Hajime Shibata hears his story and sees him die after fifty or so years.